全文获取类型
收费全文 | 7348篇 |
免费 | 174篇 |
国内免费 | 437篇 |
专业分类
化学 | 6667篇 |
晶体学 | 41篇 |
力学 | 92篇 |
综合类 | 57篇 |
数学 | 104篇 |
物理学 | 998篇 |
出版年
2024年 | 2篇 |
2023年 | 79篇 |
2022年 | 61篇 |
2021年 | 88篇 |
2020年 | 113篇 |
2019年 | 130篇 |
2018年 | 103篇 |
2017年 | 130篇 |
2016年 | 128篇 |
2015年 | 159篇 |
2014年 | 166篇 |
2013年 | 357篇 |
2012年 | 665篇 |
2011年 | 344篇 |
2010年 | 274篇 |
2009年 | 378篇 |
2008年 | 339篇 |
2007年 | 509篇 |
2006年 | 402篇 |
2005年 | 356篇 |
2004年 | 365篇 |
2003年 | 328篇 |
2002年 | 238篇 |
2001年 | 182篇 |
2000年 | 210篇 |
1999年 | 208篇 |
1998年 | 182篇 |
1997年 | 165篇 |
1996年 | 168篇 |
1995年 | 184篇 |
1994年 | 152篇 |
1993年 | 160篇 |
1992年 | 184篇 |
1991年 | 106篇 |
1990年 | 64篇 |
1989年 | 78篇 |
1988年 | 45篇 |
1987年 | 27篇 |
1986年 | 29篇 |
1985年 | 16篇 |
1984年 | 21篇 |
1983年 | 8篇 |
1982年 | 12篇 |
1981年 | 8篇 |
1980年 | 15篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1972年 | 1篇 |
1970年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有7959条查询结果,搜索用时 734 毫秒
21.
22.
开放式微波消解与干灰化法消解测量食品中铅的方法比较 总被引:1,自引:0,他引:1
对开放式微波消解法与干灰化法消解测量食品中铅的方法进行了比较,试验表明,前者操作简易,试验周期短,在测量精度和加标回收率方面两种方法无显著性差别。 相似文献
23.
24.
Erzs bet Ill s Etelka Tomb cz 《Colloids and surfaces. A, Physicochemical and engineering aspects》2003,230(1-3):99-109
The ionic strength dependence of humic acid (HA) adsorption on magnetite (Fe3O4) was investigated at pH 5, 8 and 9, where variable charged magnetite is positive, neutral and negative, respectively. The adsorption studies revealed that HA has high affinity to magnetite surface especially at lower pH, where interacting partners have opposite charges. However, in spite of electrostatic repulsion at pH 9 notable amounts of humate are adsorbed. Increasing ionic strength enhances HA adsorption at each pH due to charge screening. The dominant interaction is probably a ligand-exchange reaction, nevertheless the Coulombic contribution to the organic matter accumulation on oxide surface is also significant under acidic condition. The results from size exclusion chromatography demonstrate that the smaller size HA fractions enriched with functional groups are adsorbed preferentially on the surface of magnetite at pH 8 in dilute NaCl solution. 相似文献
25.
在前文研究的基础上,经试验,证明Ag(Ⅰ)与巯萘剂(TN)反应生成非电活性物质,导致电活性物质DTN电流降低。在最佳条件下,Ag(Ⅰ)浓度在3.7×10~(-8)~4.5×10(-7)mol/L范围内与DTN电流峰高降低值成线性关系,检出限为2.2×10~(-8)mol/L(相当于2.4ng/ml)Ag(Ⅰ)。方法用于纯镍和氢氧化钾中痕最银的测定,结果满意。 相似文献
26.
Tatiana B. Mikenas Vladimir A. Zakharov Lyudmila G. Echevskaya Mikhail A. Matsko 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5057-5066
The effects of polymerization temperature, polymerization time, ethylene and hydrogen concentration, and effect of comonomers (hexene‐1, propylene) on the activity of supported catalyst of composition LFeCl2/MgCl2‐Al(i‐Bu)3 (L = 2,6‐bis[1‐(2,6‐dimethylphenylimino)ethyl] pyridyl) and polymer characteristics (molecular weight (MW), molecular‐weight distribution (MWD), molecular structure) have been studied. Effective activation energy of ethylene polymerization over LFeCl2/MgCl2‐Al(i‐Bu)3 has a value typical of supported Ziegler–Natta catalysts (11.9 kcal/mol). The polymerization reaction is of the first order with respect to monomer at the ethylene concentration >0.2 mol/L. Addition of small amounts of hydrogen (9–17%) significantly increases the activity; however, further increase in hydrogen concentration decreases the activity. The IRS and DSC analysis of PE indicates that catalyst LFeCl2/MgCl2‐Al(i‐Bu)3 has a very low copolymerizing ability toward propylene and hexene‐1. MW and MWD of PE produced over these catalysts depend on the polymerization time, ethylene and hexene‐1 concentration. The activation effect of hydrogen and other kinetic features of ethylene polymerization over supported catalysts based on the Fe (II) complexes are discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5057–5066, 2007 相似文献
27.
28.
Protection of iron corrosion by stearic acid and stearic imidazoline self-assembled monolayers 总被引:4,自引:0,他引:4
A type of stearic imidazoline (IM) inhibitor was prepared using stearic acid (SA) and diethylenetriamine (DETA) as raw materials. The monolayers of IM and SA were assembled on the iron surface. The electrochemical characterization of stearic acid (SA) and stearic imidazoline (IM) on an oxide free iron surface had been studied. The monolayers of IM inhibitor were characterized by electrochemical impedance spectroscopy (EIS), electrochemical polarization curves, double layer capacitance, X-ray photoelectron spectroscopy (XPS) and molecular simulation. The results of electrochemical studies had illustrated that the inhibition efficiency of IM was higher than SA. XPS showed that the IM molecules adsorbed on the iron surface. The molecular simulation calculations showed that the IM molecules were tilted at an angle on the iron surface. 相似文献
29.
Corrosion-related defects of pure iron were investigated by measuring Doppler broadening energy spectra (DBES) of positron annihilation and positron annihilation lifetime (PAL). Defect profiles of the S-parameter from DBES as a function of positron incident energy up to 30 keV (i.e. ∼1 μm depth) were analyzed. The DBES data show that S-parameter increases as a function of positron incident energy (mean depth) after corrosion, and the increase in the S-parameter is larger near the surface than in the bulk due to corrosion. Furthermore, information on defect size from PAL data as a function of positron incident energy up to 10 keV (i.e. ∼0.2 μm depth) was analyzed. In the two-state trapping model, the lifetime τ2 = 500 ps is ascribed to annihilation of positrons in voids with a size of the order of nanometer. τ1, which decreases with depth from the surface to the bulk, is ascribed to the annihilation of positrons in dislocations and three-dimensional vacancy clusters. The corroded samples show a significant increase in τ1 and the intensity I2, and near the surface the corroded iron introduces both voids and large-size three-dimensional vacancy clusters. The size of vacancy clusters decreases with depth. 相似文献
30.